The valence of an atom determines its ability to gain or lose an electron, which ultimately determines the chemical and electrical properties of the atom. These properties can be categorized as being a conductor, semiconductor or insulator, depending on the ability of the material to produce free electrons. When a material has a large number of free electrons available, a greater current can be conducted in the material.
Elements such as gold, copper and silver possess many free electrons and make good conductors. The atoms in these materials have a few loosely bound electrons in their outer orbits. Energy in the form of heat can cause these electrons in the outer orbit to break loose and drift throughout the material. Copper and silver have one electron in their outer orbits. At room temperature, a piece of silver wire will have billions of free electrons.
These are materials that do not conduct electrical current very well or not at all.Good examples of these are: glass, ceramic, and plastic. Under normal conditions, atoms in these materials do not produce free electrons. The absence of the free electrons means that electrical current cannot be conducted through the material. Only when the material is in an extremely strong electrical field will the outer electrons be dislodged. This action is called breakdown and usually causes physical damage to the insulator.
This material falls in between the characteristics of conductors and insulators, in that they are not good at conducting or insulating. Silicon and germanium are the most widely used semiconductor materials.